For the systems in which only solution remained until the end of the tests, they were referred to as solution (S). The system in which the potential gelator could not be dissolved, even at the boiling point of the solvent, was designated as Selleckchem Torin 2 an insoluble system (I). Critical gelation concentration (CGC) refers to the JAK inhibitor minimum concentration of the gelator

for gel formation. Measurements Firstly, the xerogel was prepared by a vacuum pump for 12 to 24 h. The dried sample thus obtained was attached to mica, copper foil, glass, and CaF2 slice for morphological and spectral investigations. Before SEM measurement, the samples were coated with copper foil fixed by a conductive adhesive tape and shielded with gold. SEM pictures of the xerogel were taken using a Hitachi S-4800 field emission scanning electron microscope (Chiyoda-ku, Japan) with

the accelerating voltage of 5 to 15 kV. AFM images were recorded using a multimode 8 scanning probe microscope (Veeco Instrument, Plainview, NY, USA) with silicon cantilever probes. All AFM images were shown in the height mode without any image processing except flattening. Transmission Fourier transform MEK phosphorylation infrared (FT-IR) spectra of the xerogel were obtained using a Nicolet iS10 FT-IR spectrophotometer from Thermo Fisher Scientific Inc. (Waltham, MA, USA) with an average of 32 scans and at a resolution of 4 cm-1. The X-ray diffraction (XRD) measurement was conducted using a Rigaku D/max 2550PC diffractometer (Rigaku Inc., Tokyo, Japan). The XRD pattern was obtained using CuKα radiation with an incident wavelength of 0.1542 nm under a voltage of 40 kV and a current of 200 mA. The scan rate was 0.5°

min-1. 1H NMR spectra were obtained using a Bruker ARX-400 NMR spectrometer (Bruker, Inc., Switzerland) in CDCl3 with tetramethylsilane (TMS) as an Fenbendazole internal standard. The elemental analysis was carried out with the Flash EA Carlo-Erba-1106 Thermo-Quest (Milan, Italy). Results and discussion The gelation performances of all compounds in 21 solvents are listed in Table 1. Examination of the table reveals that all compounds are efficient gelators. Firstly, TC16-Azo can gel in 12 solvents, such as nitrobenzene, aniline, acetone, cyclopentanone, ethyl acetate, pyridine, and DMF. As for TC16-Azo-Me with additional methyl groups in azobenzene part, only eight kinds of organogels were formed. Secondly, as for the SC16-Azo and SC16-Azo-Me with single alkyl substituent chains in molecular skeletons, the numbers of formed organogels changed to 3 and 6, respectively. Their photographs of organogels of SC16-Azo and SC16-Azo-Me in different solvents were shown in Figure 2. The data shown in Table 1 indicate that change of substituent groups in azobenzene residue and benzoic acid derivatives can have a profound effect upon the gelation abilities of these studied compounds.