In particular, one set of parameters

can describe the beh

In particular, one set of parameters

can describe the behaviour of the magnetic field dependence for high and low oxygen coverage of the sample by changing only the parameters directly relevant to the energy transfer process. This represents the first detailed and quantitative investigation of magnetic field effects in the photogeneration of singlet oxygen by use of silicon nanoparticles and provides a model which can easily be expanded in order to investigate the dependence of the energy transfer process on nanoparticle size, excitation intensity, and temperature; this work is in progress. Acknowledgements This work was supported by the Engineering and Physical Sciences Research Council (UK) under grant EP/J007552/1. References 1. Kovalev D, Gross E, Künzner N, Koch F, Timoshenko VY, Fujii M: Resonant electronic energy transfer from excitons confined BTSA1 clinical trial in silicon nanocrystals to oxygen

molecules. Phys Rev Lett 2002, 89:137401.CrossRef 2. Gross E, Kovalev D, Kunzner N, Diener J, Koch F, Timoshenko VY, Fujii M: Spectrally resolved electronic energy transfer from silicon nanocrystals to molecular oxygen mediated by direct electron exchange. Phys Rev B 2003,68(11):115405.CrossRef 3. Kovalev D, Fujii M: Silicon nanocrystals: photosensitizers for oxygen molecules. Adv Mater 2005,17(21):2531–2544.CrossRef 4. Osminkina LA, Gongalsky MB, Motuzuk AV, Timoshenko Cilengitide VY, Kudryavtsev AA: Silicon nanocrystals as photo-

and sono-sensitizers for biomedical applications. Appl Phys B Laser Optic 2011,105(3):665–668.CrossRef 5. Xiao L, Gu L, Howell SB, Sailor MJ: Porous silicon nanoparticle photosensitizers for singlet oxygen and their phototoxicity against cancer cells. Acs Nano 2011,5(5):3651–3659.CrossRef 6. Lapkin AA, Boddu VM, Aliev GN, see more Goller Acetophenone B, Polisski S, Kovalev D: Photo-oxidation by singlet oxygen generated on nanoporous silicon in a LED-powered reactor. Chem Eng J 2008,136(2–3):331–336.CrossRef 7. Pickering C, Beale MIJ, Robbins DJ, Pearson PJ, Greef R: Optical studies of the structure of porous silicon films formed in p-type degenerate and non-degenerate silicon. J Phys C Solid State Phys 1984,17(35):6535.CrossRef 8. Canham LT: Silicon quantum wire array fabrication by electrochemical and chemical dissolution of wafers. Appl Phys Lett 1990,57(10):1046–1048.CrossRef 9. Cullis AG, Canham LT, Calcott PDJ: The structural and luminescence properties of porous silicon. J Appl Phys 1997,82(3):909–965.CrossRef 10. Timmerman D, Gregorkiewicz T: Power-dependent spectral shift of photoluminescence from ensembles of silicon nanocrystals. Nanoscale Res Lett 2012,7(1):389.CrossRef 11. Arad-Vosk N, Sa’ar A: Radiative and nonradiative relaxation phenomena in hydrogen- and oxygen-terminated porous silicon. Nanoscale Res Lett 2014,9(1):47.CrossRef 12.

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